International Journal of Occupational Hygiene 2017. 9(4):.

Applications of ultrasound assisted emulsification with solidification of floating organic droplet microextraction in the sample used of trace iron
sara karimi zeverdegani, Mitra Shabab, Masoud rismanchian, Hossein Ali Rangkooy

Abstract


Objectives: This study a novel ultrasound assisted emulsification with solidification of floating organic droplet microextraction procedure (USAE-SFODME) for iron determination was developed. USAE-SFODME method was not so far used for that aim. Thus, this method is quite innovative in this respect. The method is based on: preparation of urine samples containing iron cations, iron extraction and analysis by Flame atomic absorption spectroscopy (FAAS).

Results: The optimal experimental conditions  for the urine samples spiked containing 0.8µg ml-1 iron was found to be: 2 mL of ligand, 1-(2-Pyridylazo)-2-naphthol (PAN), 90 μL extraction solvent, temperature =35˚C, sonication of time=20 minutes in pH=5.5. LOD, RSD and recovery were obtained respectively: 0.378μg mL-1, 1.67% and 97.37% (n=9).

Conclusions: USAE-SFODME technique could be established as a successful method in determining trace of iron in urine samples. Reducing sample size, replacement of toxic reagents and reducing organic solvent, direct analysis and no requirement for sample preparation, high efficiency and reduced exposure time for the operators with toxic organic solvents are among the most prominent advantages of the proposed method.

Keywords


USAE-SFODME, Urine sample, Iron, Flame Atomic Absorption Spectroscopy

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References


Mehra R, Juneja M. Adverse health effects in workers exposed to trace/toxic metals at workplace. Indian Journal of Biochemistry and Biophysics. 2003;40(2):131-5.

Kozlowski H, Luczkowski M, Remelli M, Valensin D. Copper, zinc and iron in neurodegenerative diseases (Alzheimer's, Parkinson's and prion diseases). Coordination Chemistry Reviews. 2012;256(19):2129-41.

Viles JH. Metal ions and amyloid fiber formation in neurodegenerative diseases. Copper, zinc and iron in Alzheimer's, Parkinson's and prion diseases. Coordination Chemistry Reviews. 2012;256(19):2271-84.

Bingham E, Cohrssen B, Powell CH. Patty's toxicology. Volume 2: toxicological issues related to metals, neurotoxicology and radiation metals and metal compounds: John Wiley and Sons; 2001.

Stevens RG, Jones DY, Micozzi MS, Taylor PR. Body iron stores and the risk of cancer. New England Journal of Medicine. 1988;319(16):1047-52.

Wang B, Feng W, Zhu M, Wang Y, Wang M, Gu Y, et al. Neurotoxicity of low-dose repeatedly intranasal instillation of nano-and submicron-sized ferric oxide particles in mice. Journal of nanoparticle research. 2009;11(1):41-53.

Lund Rasmussen K, Skytte L, D'imporzano P, Orla Thomsen P, Søvsø M, Lier Boldsen J. On the distribution of trace element concentrations in multiple bone elements in 10 Danish medieval and post‐medieval individuals. American Journal of Physical Anthropology. 2016.

Kokosa JM. Recent trends in using single-drop microextraction and related techniques in green analytical methods. TrAC Trends in Analytical Chemistry. 2015;71:194-204.

Pena-Pereira F, Lavilla I, Bendicho C. Headspace single-drop microextraction with in situ stibine generation for the determination of antimony (III) and total antimony by electrothermal-atomic absorption spectrometry. Microchimica Acta. 2009;164(1-2):77-83.

Mohammadi SZ, Baghelani YM, Mansori F, Shamspur T, Afzali D. Dispersive liquid-liquid microextraction for the simultaneous separation of trace amounts of zinc and cadmium ions in water samples prior to flame atomic absorption spectrometry determination. Química Nova. 2012;35(1):198-202.

Chang Q, Zhang J, Du X, Ma J, Li J. Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination of trace amounts of copper in water samples. Frontiers of Environmental Science & Engineering in China. 2010;4(2):187-95.

Chen S, Zhu S, Lu D. Solidified floating organic drop microextraction for speciation of selenium and its distribution in selenium-rich tea leaves and tea infusion by electrothermal vapourisation inductively coupled plasma mass spectrometry. Food chemistry. 2015;169:156-61.

Moghadam MR, Shabani AMH, Dadfarnia S. Spectrophotometric determination of iron species using a combination of artificial neural networks and dispersive liquid–liquid microextraction based on solidification of floating organic drop. Journal of hazardous materials. 2011;197:176-82.

Liang P, Liu G, Wang F, Wang W. Ultrasound-assisted surfactant-enhanced emulsification microextraction with solidification of floating organic droplet followed by high performance liquid chromatography for the determination of strobilurin fungicides in fruit juice samples. Journal of Chromatography B. 2013;926:62-7.

Viñas P, Campillo N, Andruch V. Recent achievements in solidified floating organic drop microextraction. TrAC Trends in Analytical Chemistry. 2015;68:48-77.

Shrivastava A, Gupta VB. Methods for the determination of limit of detection and limit of quantitation of the analytical methods. Chronicles of Young Scientists. 2011;2(1):21.

Wu C, Zhao B, Li Y, Wu Q, Wang C, Wang Z. Development of dispersive liquid-liquid microextraction based on solidification of floating organic drop for the sensitive determination of trace copper in water and beverage samples by flame atomic absorption spectrometry. Bulletin of the Korean Chemical Society. 2011;32(3):829-35.

Moghadam MR, Shabani AMH, Dadfarnia S. Simultaneous spectrophotometric determination of Fe (III) and Al (III) using orthogonal signal correction–partial least squares calibration method after solidified floating organic drop microextraction. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015;135:929-34.

Safavi A, Abdollahi H, Mirzajani R. Simultaneous spectrophotometric determination of Fe (III), Al (III) and Cu (II) by partial least-squares calibration method. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2006;63(1):196-9.

Szabó L, Herman K, Mircescu NE, Fălămaş A, Leopold LF, Leopold N, et al. SERS and DFT investigation of 1-(2-pyridylazo)-2-naphthol and its metal complexes with Al (III), Mn (II), Fe (III), Cu (II), Zn (II) and Pb (II). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2012;93:266-73.

Tabrizi AB. Development of a dispersive liquid–liquid microextraction method for iron speciation and determination in different water samples. Journal of hazardous materials. 2010;183(1):688-93.

Bahar S, Zakerian R. Speciation of Fe (II) and Fe (III) by using dispersive liquid-liquid microextraction and flame atomic absorption spectrometry. Journal of the Brazilian Chemical Society. 2012;23(5):944-50.

Khayatian G, Hassanpoor S. Ultrasound Assisted Emulsification Microextraction Based on dimetyl (E)‐2‐[(Z)‐1‐acetyl)‐2‐hydroxy‐1‐propenyl]‐2‐butenedioate for Determination of Total Amount of Iron in Water and Tea Samples. Journal of the Chinese Chemical Society. 2012;59(5):659-66.

Khayatian G, Hassanpoor S. Development of ultrasound-assisted emulsification solidified floating organic drop microextraction for determination of trace amounts of iron and copper in water, food and rock samples. Journal of the Iranian Chemical Society. 2013;10(1):113-21.

Madadizadeh M, Taher MA, Ashkenani H. Ligandless Dispersive Liquid–Liquid Microextraction of Iron in Biological and Foodstuff Samples and Its Determination by Electrothermal Atomic Absorption Spectrometry. Journal of AOAC International. 2013;96(6):1466-72.


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