Application of Ultrasound-assisted Emulsification Solidification of Floating Organic Drop Microextraction for Preconcentration and Trace Detection of Iron (III) in Water and Human Urine Samples
,
Abstract
At present, metals are used in many industries and working places so the consequence use and exposure to toxic metals is some human health risks. In order to protect the exposed people to these metals, identification of toxic metals in biological samples can be an effective strategy in the controlling of people's health. In the present research, ultrasound-assisted emulsification with solidification of floating organic droplet microextraction procedure (USAE-SFODME) combined with atomic absorption spectroscopy was used for pre-concentration and determination trace amount of iron (III) from water and urine matrices. This research consisted of preparation of samples containing iron (III), iron extraction and analysis with flame atomic absorption spectroscopy equipped with iron hollow cathode lamp with analysis wavelength of 248.33 nanometers. Optimization of the extraction conditions was carried out for ligand volume, solvent volume, temperature, sonication time and pH. Detection of limit (LOD) and limit of quantification (LOQ) were respectively 0.378 and 1.147 μg mL-1 in this research. The proposed method in pre-concentration and analysis trace amount of iron in aquatic samples can be established as a successful method. One of the important advantages of this approach reduces the operator exposure to toxic substances.
KARGAR F, SHAHTAHERI S, GOLBABAEI F, BARKHORDARI A, RAHIMI–FROUSHANI AB. Measurement of urinary cadmium in glazers using solid phase extraction followed by inductively coupled plasma atomic emission spectroscopy. International Journal of Occupational Hygiene. 2015 Oct 11;4(2):11-6
Khadem M, Golbabaei F, RAHIMI FA, SHAHTAHERI J. Optimization of solid phase extraction for trace determination of cobalt (II) using Chromosorb 102 in biological monitoring.International Journal of Occupational Hygiene. 2010;Volume 1 , Number 2; 11-17.
Kozlowski H, Luczkowski M, Remelli M, Valensin D. Copper, zinc and iron in neurodegenerative diseases (Alzheimer's, Parkinson's and prion diseases). Coord Chem Rev 2012;256(19):2129-41.
Viles JH. Metal ions and amyloid fiber formation in neurodegenerative diseases. Copper, zinc and iron in Alzheimer's, Parkinson's and prion diseases.Coord Chem Rev 2012;256(19):2271-84.
Wang B FW, Zhu M, Wang Y, Wang M, Gu Y, et al.Neurotoxicity of low-dose repeatedly intranasal instillation of nano-and submicron-sized ferric oxide particles in mice. J Nanopart Res 2009;11(1):41-53.
Lund Rasmussen K, Skytte L, D'imporzano P, Orla Thomsen P, Søvsø M, Lier Boldsen J. On the distribution of trace element concentrations in multiple bone elements in 10 Danish medieval and post‐medieval individuals. Am J Phys Anthropol 2016.
Kokosa JM. Recent trends in using single-drop microextraction and related techniques in green analytical methods. Trends Analyt Chem 2015;71:194-204.
Pena-Pereira F, Lavilla I, Bendicho C. Headspace single-drop microextraction with in situ stibine generation for the determination of antimony (III) and total antimony by electrothermal-atomic absorption spectrometry. Mikrochim Acta 2009;164(1-2):77-83.
Mohammadi SZ, Baghelani YM, Mansori F, Shamspur T, Afzali D. Dispersive liquid-liquid microextraction for the simultaneous separation of trace amounts of zinc and cadmium ions in water samples prior to flame atomic absorption spectrometry determination. Quim Nova 2012;35(1):198-202.
Chang Q, Zhang J, Du X, Ma J, Li J. Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination of trace amounts of copper in water samples. Front Environ Sci Eng 2010;4(2):187-95.
Chen S, Zhu S, Lu D. Solidified floating organic drop microextraction for speciation of selenium and its distribution in selenium-rich tea leaves and tea infusion by electrothermal vapourisation inductively coupled plasma mass spectrometry. Food Chem 2015;169:156-61.
Moghadam MR, Shabani AMH, Dadfarnia S. Spectrophotometric determination of iron species using a combination of artificial neural networks and dispersive liquid–liquid microextraction based on solidification of floating organic drop. J Hazard Mater 2011;197:176-82.
Grob RL, Barry EF. Modern practice of gas chromatography: John Wiley & Sons; 2004.
Viñas P, Campillo N, Andruch V. Recent achievements in solidified floating organic drop microextraction. Trends Analyt Chem 2015;68:48-77.
Khayatian G, Hassanpoor S. Development of ultrasound-assisted emulsification solidified floating organic drop microextraction for determination of trace amounts of iron and copper in water, food and rock samples. J IRAN CHEM SOC 2013;10(1):113-21.
Chamsaz M AJ, Arbab-zavar MH. Preconcentration of lead using solidification of floating organic drop and its determination by electrothermal atomic absorption spectrometry. J Adv Res 2013:361-6.
Şahin ÇA TİAca. A novel solidified floating organic drop microextraction method for preconcentration and determination of copper ions by flow injection flame atomic absorption spectrometry. Anal Chim Acta 2010::83-7.
Tajik S, Taher MA. New method for microextraction of ultra trace quantities of gold in real samples using ultrasound-assisted emulsification of solidified floating organic drops. Mikrochim Acta 2011;173(1-2):249-57.
Shrivastava A, Gupta VB. Methods for the determination of limit of detection and limit of quantitation of the analytical methods. Chronicles of Young Scientists 2011;2(1):21.
Wu C, Zhao B, Li Y, Wu Q, Wang C, Wang Z. Development of dispersive liquid-liquid microextraction based on solidification of floating organic drop for the sensitive determination of trace copper in water and beverage samples by flame atomic absorption spectrometry. Bull Korean Chem Soc 2011;32(3):829-35.
Moghadam MR, Shabani AMH, Dadfarnia S. Simultaneous spectrophotometric determination of Fe (III) and Al (III) using orthogonal signal correction–partial least squares calibration method after solidified floating organic drop microextraction. Spectrochim Acta A Mol Biomol Spectrosc 2015;135:929-34.
Safavi A, Abdollahi H, Mirzajani R. Simultaneous spectrophotometric determination of Fe (III), Al (III) and Cu (II) by partial least-squares calibration method. Spectrochim Acta A Mol Biomol Spectrosc 2006;63(1):196-9.
Szabó L, Herman K, Mircescu NE, Fălămaş A, Leopold LF, Leopold N, et al. SERS and DFT investigation of 1-(2-pyridylazo)-2-naphthol and its metal complexes with Al (III), Mn (II), Fe (III), Cu (II), Zn (II) and Pb (II). Spectrochim Acta A Mol Biomol Spectrosc 2012;93:266-73.
Tabrizi AB. Development of a dispersive liquid–liquid microextraction method for iron speciation and determination in different water samples. J Hazard Mater 2010;183(1):688-93.
Pehlivan E, Kara D. Iron speciation by solid phase extraction and flame atomic absorption spectrometry using N, N′-bis-(2-hydroxy-5-bromobenzyl)-2-hydroxy-1, 3-diiminopropane. Mikrochim Acta 2007;158(1-2):137-44.
Sobhi HR, Kashtiaray A, Farahani H, Javaheri M, Ganjali MR. Quantitation of mononitrotoluenes in aquatic environment using dispersive liquid–liquid microextraction followed by gas chromatography–flame ionization detection. J Hazard Mater 2010;175(1):279-83.
Saçmacı Ş, Kartal Ş. Selective extraction, separation and speciation of iron in different samples using 4-acetyl-5-methyl-1-phenyl-1H-pyrazole-3-carboxylic acid. Anal Chim Acta 2008;623(1):46-52.
Madadizadeh M, Taher MA, Ashkenani H. Ligandless Dispersive Liquid–Liquid Microextraction of Iron in Biological and Foodstuff Samples and Its Determination by Electrothermal Atomic Absorption Spectrometry. J AOAC Int 2013;96(6):1466-72.
| Files | ||
| Issue | Vol 9 No 4 (2017) | |
| Section | Original Article(s) | |
| Published | 2017-10-16 | |
| Keywords | ||
| USAE-SFODME Urine sample Iron Flame Atomic Absorption Spectroscopy | ||
| Rights and permissions | |
|
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. |
